It sounds like you are asking basic VOR navigation. I guess you don't want to fly like the real airlines! only kidding. This is what I do:
-File the plan and look at the heading to each waypoint
-If I'm flying to a VOR, I track the radial that is the reciprical of the heading in the planner. (ie, hdg170, track radial 350 to the VOR)
-If I'm flying to an intersection, I track the radial AWAY from the VOR I just left (ie the radial and planner heading will match)
- If there are more than one intersection in a row it can get tricky, but usually they can just be ignored and used as a method of determining progress.
The VOR frequencies are under the map view (world menu). Intersections do not have frequencies, they are an imaginary point in space where two radials from two different VORs intersect. I find them difficult to locate on the airliners because you have to use both NAV radios, and the NAV2 on airliners is just a pointer. It doesn't really tell you if you are on a radial.
Did I confuse you? You can learn here:
http://www.navfltsm.addr.com/vor-nav.htm