
Prop sync is to do with engine revs.
If the revs of each engine aren't quite the same you get a resonnance. You know, sounds like
vooom vooom vooomYou must have heard it

The closer the engine revs are, the slower the waves of the resonnance become until when the revs are exactly equal, it disappears.
You can adjust the throttles manually but by hitting prop sysnc, it does it for you so you can avoid the at least annoying, but potentially damaging, resonnance