PCI Express has more bandwith... but isn't specifically for graphics cards.
PCI-E 16 (the large ones) have the most bandwith, and are often used for graphics cards. Some chipsets support 2 of these and if they are available on the bouard, you can run a SLI GeForce setup
The smaller ones are PCI-E 4, and have less bandwith available (but still more compared to standard PCI-33)
The other odd normal PCI slots available are
- PCI-32 5 Volt, with a different key gap. Have been used in the past by Apple.
- PCI-64 5 Volt, key same as with a 5 volt PCI-32, but same length as an ISA
- PCI-64 3,3 Volt, key same as the normal PCI-32 (which is a 3,3 volt), but with the extension.
Most PCI-64 slots can handle a PCI-32 card, but you need a special card if you want to have one that works in both 32 and 64 bit (like the Adaptec SCSI-160 adapter they once sold, which works in both, but is slower in the PCI-32 slots)