One thing I do recommend is to not slipstream anything into the OS other than SP2 and IE7. I do recall there were problems with x64SP2 and the use of nlite and other slipstream applications which were causing file corruption issues. I do not know if those were ever resolved.
Thanks for the replies NickN,
Well, I've been running the nilte slipstream since I last posted with no issues as far as I can tell, everything seems to be working properly except my old sidewinder joystick.
I integrated SP2, IE7 and all the critical updates for XPx64 into that install disk, then I ran a vulnerability scan and the system came up with a green light, all patched and secure

Not sure if I'll bother installing another RAID-0 with XPx64, running it on a 320gb drive now.
I've only just returned home, sorry about the late reply.

Mainboard: Asus P5K-Premium, CPU=Intel E6850 @ x8x450fsb 3.6ghz, RAM: 4gb PC8500 Team Dark, Video: NV8800GT, HDD: 2x1Tb Samsung F3 RAID-0 + 1Tb F3, PSU: Antec 550 Basiq, OS: Win7x64, Display: 24&